Molecular Orbital theory
Monday, 3 November 2014
THE THREE CENTERED TWO ELECTRON BOND
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A three centered two electron bond as name suggest speaks about three centres sharing two electrons to make one bond. These type of bondi...
BUILDING Formaldehyde
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• Oxygen p orbitals are lower energy than the CH2 p orbital. • MO’s analogous to key orbitals in ethylene are formed including both th...
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Effects of Heteroatoms - Formaldehyde
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• Rule 5: Molecules with similar structures will have qualitatively similar MO’s, with the major difference being the number of valence ē...
Ethylene
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• Standard bonding picture for ethylene is viewed as being made from 2 sp2 hybridized C atoms, and consists of a C-C double bond. • MOT...
Ethane
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• As molecules get bigger constructing the molecular orbitals becomes more challenging. • Insights into bonding of larger molecules can b...
Orbital Mixing - Building Larger Molecules
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• Essence of orbital mixing is stated in Rules 8 and 9. • Rule 8: When two orbitals interact, the lower energy orbital is stabilized and ...
The CH2/MH2 Group
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THEORY FOR CH2 IS SAME AS CH3 SO I HAVE EXPLAINED IT IN SHORT IF U STILL HAVE DOUBT COMMENT BELOW. • Generate group orbitals for CH2 grou...
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